Hydrate Inhibitor Requirements Calculator

Calculates required inhibitor concentration in free water and injection rate for hydrate prevention via hydrate formation temperature depression using common industry practice correlations (Hammerschmidt + Nielsen-Bucklin for methanol/water). Use for engineering screening; final dosage should be confirmed against project design basis and vendor / operations guidance.

Temperature & Hydrate Margin

Inhibitor Selection

Free Water & Injection Basis

Actions

Results

Required Inhibitor in Water (W): - wt%
Required Depression (d): - Β°C ( - Β°F )
Method Used: -
Free Water Rate (converted): - kg/h
Active Inhibitor Required: - kg/h
Injected Liquid Required (with conc. & losses): - kg/h
Injected Liquid Volumetric Rate: - L/h
Total Injected Liquid (Period): - kg ( - L )
Warning: This calculator is for engineering screening. Hydrate risk management is highly system-specific (composition, pressure, kinetics, subcooling distribution, water holdup, pigging, dead-legs). Always confirm with the project hydrate/dehydration basis and operations/vendor recommendations.

Technical Notes

Variable Definitions

  • Thyd: Hydrate formation temperature at controlling pressure/composition (Β°C).
  • Top: Minimum operating (flowing) temperature at risk location (Β°C).
  • margin: Additional depression safety margin (Β°C).
  • d: Required temperature depression, d = (Thyd βˆ’ Top) + margin.
  • W: Required inhibitor concentration in free water (wt% inhibitor in water phase).
  • ṁw: Free water mass rate at risk location (kg/h).
  • ṁinh: Active inhibitor mass rate required to achieve W in water (kg/h).
  • C: Injected liquid active concentration (wt%).
  • lossFactor: Allowance for distribution/vaporization/handling losses (β‰₯ 1.0).
  • ṁinj: Injected liquid mass rate including solution concentration and losses (kg/h).
  • Qinj: Injected liquid volumetric rate (L/h).

Formulas / Logic

  • Required depression: d(Β°C) = (Thyd βˆ’ Top) + margin; d(Β°F)=d(Β°C)Β·9/5.
  • Hammerschmidt screening (wt% in water): W = 100Β·MΒ·d /(K + MΒ·d), where K is in Β°F and d is in Β°F.
  • Nielsen–Bucklin (methanol/water screening): d = βˆ’72Β·ln(1βˆ’x) β‡’ x = 1 βˆ’ exp(βˆ’d/72), then convert x to wt%.
  • Active inhibitor to treat free water: ṁinh = ṁwΒ·W/(100βˆ’W).
  • Injected liquid including concentration and losses: ṁinj = ṁinhΒ·lossFactor /(C/100).
  • Volumetric rate: Qinj(L/h) = 1000·ṁinj(kg/h)/ρ.
These are common engineering screening correlations for thermodynamic inhibition. Final chemical rates should be confirmed with the project flow assurance basis and chemical vendor.

Assumptions / Notes

  • Assumes inhibitor ultimately mixes with the free water phase at the risk location; does not model slip, stratification, or limited mixing.
  • Does not account for methanol partitioning to gas/hydrocarbon phases or inhibitor consumption; use lossFactor for screening and confirm with vendor.
  • Free water conversion assumes water density β‰ˆ 1000 kg/mΒ³ (screening).
  • If d ≀ 0, the method indicates no thermodynamic inhibitor is required (still confirm hydrate curve and operational margins).
  • Correlations have range limitations (e.g., methanol concentration and temperature range). Warnings indicate possible range exceedance.

Standards / References

  • Common flow assurance practice for thermodynamic hydrate inhibition (Hammerschmidt-type and methanol Nielsen–Bucklin style screening correlations).
  • Project/company hydrate management basis and chemical vendor guidelines should govern final selection.
  • Hydrate formation temperature Thyd should come from a validated hydrate curve/phase envelope (e.g., approved simulator or project study).
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